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Not sure why you post this question here. I think pathway and process are very similar, maybe sometimes overlapping.
However, the pathway maybe exclusively used in the bioology and chemistry domain, whereas the process is a more general concept for broader domain. So there maybe a need for distinguishing the pathway and process in the bio and chemistry domain, but if it outside of this domain, we use process instead.
What do you think of my approach?
Pathway & Process
Specifically in the context of biology and chemistry:
TL;DR
Process - the focus is on the outcome or end state
Pathway - the focus is on the different paths that can be taken for the outcome.
Reference
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